Introduction Application Properties Advantage Of Using Nanotechnology

Coating of part surfaces have been usually done for enhancing the corrosion resistance of metallic components and equipment. Imposing conversional coatings is one the most cost-effective conventionally applied techniques that increase pigment adhesion to surface as well as increasing corrosion resistance. Phosphate and Chromate-based conversional coatings are two frequently-used types of such protective coatings. Taking remarks such as environmental concern, health care and process cost into consideration, attempts have been made to take the advantage of other alternative coatings like oxides of zirconium, titanium and vanadium instead of old phosphate and chromate-based ones. In contrary to phosphate and chromate-based coatings, zirconium-based ones are with no environmental hazard and process can be carried out at ambient temperature in a more reasonable time period. Having a relatively lower weight of these novel zirconium-based coatings is another superior property of them over the conventional phosphate/chromate-based materials. Furthermore, there is no need of sludge neutralization in deposition of zirconium-based coating in which a required process in exposing phosphate or chromate-based conversional coatings.

Applying thin zirconium-based conversional coatings (in nano-scale) over steel, aluminum or galvanized substrate leads to enhancement in performance parameters such as adhesion, corrosion resistance as well as increase in cathodic rupture of pigment.

  • Achievement of coating with thickness less than 100 nm in metal surface
  • Applicable at ambient temperature
  • No human health hazardous waste produced
  • Cost affectivity

Coating of steel, aluminum and galvanized substrate

Application of zirconium-based nano-coating causes a significant improvement to corrosion and increase in substrate/coating adhesion.

Performing salt spray test in both samples with and without zirconium coating indicates significant improvement of corrosion resistance in one having coating. Based on achieved results, assigning coating to class 10 and 0 represents higher and lowest resistance to corrosion and delamination, correspondingly.

SampleCorrosionRupture
Sample without nano zirconia coating65
Sample with nano zirconia coating1010

According to remark 4-2 of ISO 27687 and remark 27-2 of Iranian national standard number 12098, the nano-scale zirconia-based conversional coating as the replacement of conventional phosphate/chromate coatings entails nano-plate and can be considered as a product in nanotechnology field as well.

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